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BOILER WATER PROBLEM & THEIR TREATMENT



PROBLEM
TREATMENT
O2
Mechanically: By de-aerating equipment
Chemically: By adding Sodium sulphite or Hydrazine
2Na2SO3 + O2 ® 2Na2SO4
 N2H4 + O2 ® 2H2O + N2
Acid corrosion
By lime [Ca(OH)2] and soda ash [Na2CO3] treatment:
MgCl2 + Ca(OH)2 ® Mg(OH)2 + CaCl2
CaCl2 + Na2CO3 ® CaCO3 + 2 NaCl      (CaCO3 & NaCl are dissolved salt)
Alkalinity
Caustic soda [NaOH] & Na2CO3
Caustic cracking
Na2SO4 & NaNO3
Scale
Sodium phosphate [Na3PO4]
Phosphate treatment
Tri-sodium phosphate [ Na3(PO4)2], sodium hexa-meta phosphate, sodium meta phosphate, Di-sodium phosphate
CaSO4 + Na3(PO4)2 ® Ca3(PO4)2 + Na2SO4
Sludge
Sodium aluminate, poly electrolyte, starch, tannins.
Foaming
Antifoam chemical

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